|

Laser photoacoustic analysis of complex gas mixtures

Authors: Gorodnichev V.A., Belov M.L., Fedotov Yu.V., Eremenko L.N. Published: 03.09.2015
Published in issue: #4(103)/2015  
DOI: 10.18698/0236-3933-2015-4-34-48

 
Category: Instrument Engineering, Metrology, Information-Measuring Instruments and Systems | Chapter: Instrumentation and Methods to Control Environment, Substances, Materials, and Products  
Keywords: laser method, photoacoustics, complex gas mixtures, quantified gas analysis, Bayesian estimators

The paper considers the problem of estimating the gas components concentration by multispectral laser photoacoustic measurements of complex gas mixtures, where gas components exist, which are either without pronounced maximum within the absorption spectrum or with the concentrations, which are much less than those containing more other gas components. The paper describes both the mathematical simulation results and the experimental results obtained on the laboratory measurement setup based on the laser photo acoustic gas sensor. A comparative analysis of the processing methods for the gas concentration estimation is carried out using the data obtained by multispectral laser photoacoustic measurements. It is shown that in the case of complex gas mixtures the method based on Bayesian estimator for solving the equation of laser photoacoustic gas analysis provides the smallest error in reconstruction of the gas components.

References

[1] Ponomarev Yu.N., Ageev B.G., Zigrist M.V., Kapitanov V.A., Kurtua D., Nikiforova O.Yu. Lazernaya optiko-akusticheskaya spektroskopiya mezhmolekulyarnykh vzaimodeystviy v gazakh [The Laser Photoacoustic Spectroscopy of Intermolecular Interactions in Gases]. Tomsk, MGP "RASKO" Publ., 2000. 200 p.

[2] Kozintsev V.I., Belov M.L., Gorodnichev V.A., Fedotov Yu.V. Lazernyy optiko-akusticheskiy analiz mnogokomponentnykh gazovykh smesey [The Laser Photoacoustic Analysis of Multi-Component Gas Mixtures]. Moscow, MGTU im. N.E. Baumana Publ., 2003. 352 p.

[3] Kozintsev V.I., Belov M.L., Gorodnichev V.A., Fedotov Yu.V. Osnovy kolichestvennogo lazernogo analiza [Principles of Quantitative Laser Analysis]. Moscow, MGTU im. N.E. Baumana Publ., 2006. 464 p.

[4] Uotila J., Koskinen V, Kauppila J. Selective differential photoacoustic method for trace gas analysis. Vibrational spectroscopy, 2005, vol. 38, pp. 3-9.

[5] Bageshwar D.V., Pawar A.S., Khanvilkar V.V., Kadam V.J. Photoacoustic Spectroscopy and Its Applications. Eurasian J. Anal. Chem., 2010, vol. 5 (2), pp. 187-203.

[6] Elia A., Lugara P.M., Di Franco C., Spagnolo V. Photoacoustic Techniques for Trace Gas Sensing Based on Semiconductor Laser Sources. Sensors, 2009, vol. 9, pp. 9616-9628.

[7] Holthoff E., Bender J., Pellegrino P., Fisher A. Quantum Cascade Laser-Based Photoacoustic Spectroscopy for Trace Vapor Detection and Molecular Discrimination. Sensors, 2010, vol. 10, pp. 1986-2002.

[8] Bratu A.M., Petrus M., Patachia M., Dumitras D.C. Carbon Dioxide and Water Vapors Detection from Surgical Smoke by Laser Photoacoustic Spectroscopy. U.P.B. Sci. Bull., Ser. A, 2013, vol. 75, iss. 2, pp. 139-146.

[9] Dumitras D.C., Bratu A.M., Popa C. CO2 Laser Photoacoustic Spectroscopy: I. Principles. Availlable at: http://cdn.intechopen.com/pdfs-wm/32631.pdf (accessed 20.02.2015).

[10] Hueglin C., Fischer A., Graf P., Schwarzenbach B., Buchmann B. Measurement of Ammonia in Ambient Air using Photoacoustic Spectroscopy. Availlable at: http://www.ecophysics.com/data/leaflets/Hueglin_etal_Poster%20UAQ2005.pdf (accessed 20.02.2015).

[11] Michaelian K.H. Photoacoustic IR Spectroscopy: Instrumentation, Applications and Data Analysis, Second Edition. Weinheim, Wiley-VCH Verlag GmbH & Co. KGaA, 2010. 385 p.

[12] Ageev B.G., Ponomarev Yu.N., Sapozhnikova V.A. Laser Photoacoustic Method for Disc Tree-Ring Gas Analysis. World Environment, 2012, vol. 2, no. 2, pp. 4-10.

[13] Present Approaches to Solving Ill-Posed Problems. Availlable at: http://pelbook.narod.ru/2004/02.htm (accessed 20.11.2014).

[14] Neubauer A. Inverse and Ill-Posed Problems. 2008. Availlable at: http://www.impan.pl/BC/Arch/2008/08NeubauerCourse.pdf (accessed 20.02.2015).

[15] Kataev M.Yu., Boychenko I.V. Programmnoe i metodicheskoe obespechenie zadach lidarnogo zondirovaniya atmosfery [Software and Methodical Support of Lidar Atmosphere Sensing]. Tomsk: STT Publ., 2007. 246 p.

[16] Eremenko L.N., Kozintsev V.I., Gorodnichev V.A. Bayesian Estimate Method in the Problem of Laser Gas Analysis. Izv. Vyssh. Uchebn. Zaved., Fizika. [Proc. Univ., Physics], 2008, no. 9, pp. 29-35 (in Russ.).